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Energy in Chemical Bonds

A five-day high school chemistry unit exploring thermochemistry, collision theory, enthalpy diagrams, and calorimetry through the lens of body heat and chemical reactions. Students investigate the anchoring phenomenon of exercise-induced heat while mastering TEKS C.13 standards.

OMOlutoyin Makinde
Hess Pathfinders

Students discover the additive nature of enthalpy through a hands-on chemical puzzle, using Hess's Law to calculate enthalpy changes for complex reactions using multiple intermediate steps.

Color of Heat

Students investigate the anchoring phenomenon of body heat during exercise, observe the high-energy Sugar Cube Fireworks demonstration, and prepare for thermodynamic investigations.

Phase Shift Secrets

A high-energy, station-based lesson where students investigate the thermodynamics of phase changes. Students analyze intermolecular forces to explain why melting is endothermic and freezing is exothermic, using evidence from heating curves and molecular models.

Hand Warmer Hunt

A whole-group inquiry lab where students measure temperature changes in different chemical solutions to design effective hand warmers, focusing on system-surroundings heat transfer.

Crystal Collapse

A quantitative investigation into latent heat. Students use calorimetry data to calculate the enthalpy of fusion for ice and model the molecular-level energy transitions that occur during phase change plateaus.

Collision Shuffle

A station-rotation lesson where students model molecular collisions, sort enthalpy diagrams, and practice bond energy calculations through interactive group work.

Energy Landscapes

Students develop and evaluate models for exothermic and endothermic reactions, using literacy strategies to deepen their understanding of enthalpy changes.

Thermal Showdown

A comprehensive review day featuring a thermochemistry game board and revisiting the anchoring phenomenon to evaluate mastery of energy in chemical bonds.

Energy in Chemical Bonds

A five-day high school chemistry unit exploring thermochemistry, collision theory, enthalpy diagrams, and calorimetry through the lens of body heat and chemical reactions. Students investigate the anchoring phenomenon of exercise-induced heat while mastering TEKS C.13 standards.

OMOlutoyin Makinde

\(2C(s) + 2H_2(g) + O_2(g) \rightarrow HC_2H_3O_2(l)\)

(1) \(HC_2H_3O_2(l) + 2O_2(g) \rightarrow 2CO_2(g) + 2H_2O(l)\) \(\Delta H = -875 \text{ kJ}\)

(2) \(C(s) + O_2(g) \rightarrow CO_2(g)\) \(\Delta H = -394.51 \text{ kJ}\)

(3) \(H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(l)\) \(\Delta H = -285.8 \text{ kJ}\)

Execution Plan:

ActionReason / LogicNew \(\Delta H\) Value
Mod Rxn 1Align \(HC_2H_3O_2\) as a product.
Mod Rxn 2Get \(2\) moles of Carbon as a reactant.
Mod Rxn 3Get \(2\) moles of \(H_2\) as a reactant.

Summation Zone (Ensure all spectators cancel):

Formation Enthalpy \(\Delta H_f^\circ\) =

04

Mission: Hydrogen Cyanide Synthesis

TARGET EQUATION:

\(CH_4(g) + NH_3(g) \rightarrow HCN(g) + 3H_2(g)\)

(A) \(N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)\) \(\Delta H = -91.8 \text{ kJ}\)

(B) \(C(s) + 2H_2(g) \rightarrow CH_4(g)\) \(\Delta H = -74.9 \text{ kJ}\)

(C) \(H_2(g) + 2C(s) + N_2(g) \rightarrow 2HCN(g)\) \(\Delta H = +270.3 \text{ kJ}\)

Analysis Recon:

Part 1: \(NH_3\)

Target needs \(1\) mole reactant. (A) has \(2\) mole product. Action:

Part 2: \(CH_4\)

Target needs \(1\) mole reactant. (B) has \(1\) mole product. Action:

Part 3: \(HCN\)

Target needs \(1\) mole product. (C) has \(2\) mole product. Action:

Detailed Mathematical Workspace:

MISSION SUCCESS ENTHALPY =

Model A

Enthalpy (H) Reaction Progress Reactants Products ΔH < 0

Energy is released to the surroundings. The products have lower enthalpy than the reactants.

Model B

Enthalpy (H) Reaction Progress Reactants Products ΔH > 0

Energy is absorbed from the surroundings. The products have higher enthalpy than the reactants.

Final Conclusion: Summarize the flow of energy between the SYSTEM (baggie contents) and the SURROUNDINGS (hands/air).

Step 2: Melting Ice

Step 3: Warming Water

Final Cumulative Result:

"The melting plateau (segment B) will be the same length for both experiments because the melting point of water is always 0°C."

Is this statement valid or invalid? Explain.

Thermal Logic Set

9

Vocabulary

Phase Matching

Match the process to the correct energy term:

Freezing Exothermic

Melting

Condensing

Boiling

Thermal Logic Set

10

Graph Interpretation

Energy Tally

Looking at the heating curve of water, which segment is longest on the x-axis (Heat Absorbed)?

Fusion (Melting)

Vaporization (Boiling)

Why is this specific transition so much longer than the other?

Thermal Logic Set

11

Quick Math

Temperature Shift

You add 83.6 Joules of heat to 1.0 gram of liquid water at 20°C.

Cp = 4.18 J/g°C

What is the final temperature of the water?

Thermal Logic Set

12

Synthesis

The Mastery Challenge

Which process requires MORE energy for 100 grams of water?

Choice A:

Heating water from 0°C to 100°C.


Choice B:

Vaporizing the water at 100°C.

Show your logic!

Thermal Logic Set

Task A Demand (Joules) =

Joules

Task B Cost/Gram (J/g) =

J/g

Final Mass =

grams

ΔH =

LEVEL 3 4. ETHENE HYDROGENATION

Hint: Ethene (\( \text{C}_2\text{H}_4 \)) has 1 \( \text{C=C} \) and 4 \( \text{C-H} \) bonds. Ethane (\( \text{C}_2\text{H}_6 \)) has 1 \( \text{C-C} \) and 6 \( \text{C-H} \) bonds.

Equation: \( \text{C}_2\text{H}_4 + \text{H}_2 \rightarrow \text{C}_2\text{H}_6 \)

Reactants (+)

Products (-)

ΔH =

LEVEL 4 Independent Technical Challenges

5. DECOMPOSITION OF HYDROGEN PEROXIDE

2 \(\text{H-O-O-H}\) → 2 \(\text{H-O-H}\) + \(\text{O=O}\)

ΔH =

kJ

6. COMBUSTION OF PROPANE

\( \text{C}_3\text{H}_8 + 5\text{O}_2 \rightarrow 3\text{CO}_2 + 4\text{H}_2\text{O} \)

Propane (\( \text{C}_3\text{H}_8 \)) has 2 \( \text{C-C} \) bonds and 8 \( \text{C-H} \) bonds.

ΔH =

kJ

2. Partially Assisted

Intermediate

Breaking bonds: 1,200 kJ/mol. Forming bonds: 400 kJ/mol.

ΔH = _______________

Endo

Exo

3. Independent Calculation

Advanced

"The energy cost to break reactants is 850 kJ/mol. The energy profit from forming products is 1,100 kJ/mol."

4. Phenomenon: Why Exercise Makes You Hot

Synthesis

Glucose breakdown in muscles: Energy to break reactant bonds = 1,250 kJ/mol. Energy released when forming product bonds = 2,805 kJ/mol.

Calculate net ΔH:

Why does your temperature rise?

© 2026 Lenny Education

MaterialSpecific Heat (c)Final Water Temp
Iron0.4530 deg C
Aluminum0.9036 deg C
Wood1.7041 deg C

Which material has the HIGHEST specific heat?

08. Metals conduct heat very well. Which hypothesis explains this?

They have low specific heats and change temperature easily

They have high specific heats and resist temperature change

Section 5: Flow and Boundaries

Guided Example

Heat Direction Rule:

Heat always flows from High Temperature to Low Temperature. It stops when both objects are the same temperature (Thermal Equilibrium).

09. Heat flow mission: A 40 degree object touches a 10 degree object.

Heat flows FROM:

TO:

Process STOPS at:

10. Boundary Identification: Burner heating a water beaker.

Burning Propane Gas:

SYSTEM / SURR?

The Beaker & Water:

SYSTEM / SURR?

Section 6: Final Review (11 - 16)

11. Phase Change direction: Converting liquid water to water vapor.

Endothermic

Exothermic

12. Surroundings (Water) starts at 58 degrees and ends at 61 degrees.

Reaction was ENDO

Reaction was EXO

13. Calculation: Find Delta T for water heated from 20.0 to 35.0 degrees C.

Workspace (Final Temp - Initial Temp)

Delta T = _______ degrees C

14. Mission: Solve the missing coefficients.

2 C4H10 + 13 O2 →

?

CO2

?

H2O

Strategy: 8 carbons on the left = 8 carbon dioxide molecules.

15. If Reaction [ A + B → C ] has Delta H = -100 kJ.
What is Delta H for the reverse: [ C → A + B ]?

Logic Workspace

Delta H = __________ kJ

16. Connectivity Challenge:

Explain how Activation Energy (Ea) acts as a security gate. How does increasing the temperature help more molecules get through this gate faster?

Burning Propane:
SYSTEM

Water/Beaker:
SURROUNDINGS

Mission 11: Phase Logic

Answer: ENDOTHERMIC

Worked Example Logic: Liquid molecules must absorb heat from the surroundings to break intermolecular bonds and move into the gas phase.

Mission 12: Temperature Shift

Answer: EXOTHERMIC

Proof: The thermometer (surroundings) increased in temperature, proving heat exited the reaction system.

Mission 13: Delta T Result

Answer: 15.0 deg C

Calculations: 35.0 (Final) - 20.0 (Initial) = 15.0.

Mission 14: Equation Mastery

2 C4H10 + 13 O2 → 8 CO2 + 10 H2O

Mission 15: Direction Switch

Answer: +100 kJ

Explanation: Reversing the chemical equation mathematically reverses the enthalpy sign.

Mission 16: Synthesis logic

Model Answer: Activation Energy (Ea) acts as an energy barrier that prevents reactants from turning into products immediately. Higher temperature adds kinetic energy, making molecules faster and more forceful, allowing them to overcome this barrier more frequently.

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